a) \(n_{Al_2O_3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

           0,4<--0,3<---------0,2

=> m_Al = 0,4.27 = 10,8(g)

b) C1: V_O2 = 0,3.22,4 = 6,72(l)

C2: Theo ĐLBTKL: m_O2 = 20,4 - 10,8 = 9,6(g)

=> \(n_{O_2}=\dfrac{9,6}{32}=0,3\left(mol\right)=>V_{O_2}=0,3.22,4=6,72\left(l\right)\)

c) V_kk = 6,72 : 20% = 33,6(l)

a. Ag không phản ứng nên ta có PTHH: \(2Mg+O_2\rightarrow^{t^o}2MgO\)

\(\rightarrow m_{O_2}=m_{hh}-m_{\mu\text{ối}}=18,8-15,6=3,2g\)

\(\rightarrow n_{O_2}=\frac{3,2}{32}=0,1mol\)

b. \(\rightarrow V_{O_2}=n.22,4=22,4.0,1=2,24l\)

\(\rightarrow V_{kk}=4,48.5=11,2l\)

c. Có \(n_{Mg}=2n_{O_2}=0,2l\)

\(\rightarrow m_{Mg}=0,2.24=4,8g\)

\(\rightarrow\%m_{Mg}=\frac{4,8.100}{15,6}\approx30,77\%\)

\(\rightarrow\%m_{Ag}=100\%-30,77\%=69,23\%\)

PTHH: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

             \(CO_2+Ba\left(OH\right)_2\rightarrow BaCO_3\downarrow+H_2O\)

Ta có: \(n_{H_2O}=\dfrac{7,2}{18}=0,4\left(mol\right)\) 

\(\Rightarrow\left\{{}\begin{matrix}n_{CO_2}=n_{BaCO_3}=0,2\left(mol\right)=n_{CH_4}\\n_{O_2}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{BaCO_3}=0,2\cdot197=39,4\left(g\right)\\V_{CH_4}=0,2\cdot22,4=4,48\left(l\right)\\V_{kk}=\dfrac{0,4\cdot22,4}{20\%}=44,8\left(l\right)\end{matrix}\right.\) 

a, \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

PT: \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

Theo PT: \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,15\left(mol\right)\Rightarrow V_{O_2}=0,15.24,79=3,7185\left(l\right)\)

\(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{20\%}=18,5925\left(l\right)\)

b, Theo PT: \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,1\left(mol\right)\Rightarrow m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)

a)\(n_{Al}=\dfrac{5,4}{27}=0,2\left(m\right)\)

\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

tỉ lệ       :4          3        2

số mol  :0,2       0,15   0,1

\(V_{O_2}=0,1.22,4=2,24\left(l\right)\)

\(V_{kk}=\dfrac{2,24.20\%}{100\%}=11,2\left(l\right)\)

PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

_____0,9___0,6______0,3 (mol)

a, \(V_{O_2}=0,6.22,4=13,44\left(l\right)\)

b, \(m_{Fe}=0,9.56=50,4\left(g\right)\)

c, \(V_{kk}=\dfrac{V_{O_2}}{20\%}=67,2\left(l\right)\)

nC2H5OH=0,2 mol

C2H5OH+3 O2 =>2CO2+3H2O

0,2 mol =>0,6mol=>0,4 mol

VCO2=0,4.22,4=8,96l

VO2=0,6.22,4=13,44l

=>Vkk=13,44/20%=67,2 lit

\(n_{P_2O_5}=\dfrac{21,3}{142}=0,15\left(mol\right)\)

PTHH: 4P + 5O₂ --to--> 2P₂O₅

            0,3    0,375         0,15

\(\rightarrow\left\{{}\begin{matrix}m_P=0,3.31=9,3\left(g\right)\\V_{O_2}=0,375.22,4=8,4\left(l\right)\\V_{kk}=8,4.5=42\left(l\right)\end{matrix}\right.\)

PTHH: 2KClO₃ --to--> 2KCl + 3O₂

          0,25                              0,375

=> m_KClO3 = 0,25.122,5 = 30,625 (g)

\(nP_2O_5=\dfrac{21,3}{142}=0,15\left(mol\right)\)

\(pthh:4P+5O_2-t^o->2P_2O_5\)
           0,3     0,375                0,15
=> \(m_P=0,3.31=9,3\left(g\right)\)
=>\(V_{O_2}=0,375.22,4=8,4\left(L\right)=>V_{KK}=8,4:20\%=42\left(L\right)\)
\(pthh:2KMnO_4-t^o->K_2MnO_4+MnO_2+O_2\) 
           0,75                                                 0,75 
=> mKMnO4 = 0,75 . 158 = 118,5 (G)                                                   

\(m_{Al}=27,8.19,2\%=5,4\left(g\right)\\ m_{Fe}=27,8-5,4=22,4\left(g\right)\\ \rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\end{matrix}\right.\)

PTHH:

4Al + 3O₂ --t^o--> 2Al₂O₃

0,2-->0,15------->0,1

3Fe + 2O₂ --t^o--> Fe₃O₄

0,4-->4/15--------->2/15

\(\rightarrow\left\{{}\begin{matrix}V_{kk}=\left(0,15+\dfrac{4}{15}\right).22,4.5=\dfrac{140}{3}\left(l\right)\\m_{Cran}=0,1.102+\dfrac{2}{15}.232=\dfrac{617}{15}\left(g\right)\end{matrix}\right.\)

mAl=27,8.19,42%=5,4g

⇒nAl=\(\dfrac{5,4}{27}\)=0,2mol

⇒nFe=\(\dfrac{27,8-5,4}{56}\)=0,4mol

4Al+3O2to→2Al2O34

3Fe+2O2to→Fe3O4

⇒nO2=\(\dfrac{3}{4}\)nAl+\(\dfrac{2}{3}\)nFe=\(\dfrac{5}{12}\)mol

⇒Vkk=\(\dfrac{5}{12}\).22,4.5=46,67l

b,

mrắn=27,8+mO2=27,8+​​\(\dfrac{5}{12}\)32=41,1g

→⎧⎪ ⎪ ⎪⎨⎪ ⎪ ⎪⎩Vkk=(0,15+415